Bis(nitrato-κO)[(S)-2-(pyrrolidin-2-yl)-1H-benzimidazole]cadmium(II)
نویسندگان
چکیده
The title compound, [Cd(NO(3))(2)(C(11)H(13)N(3))(2)], was synthesized by hydro-thermal reaction of Cd(NO(3))(2) and S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole. The Cd atom lies on an inversion centre. The distorted octa-hedral Cd environment contains two planar trans-related N,N-chelating S-2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in one plane and two monodentate nitrate ligands. N-H⋯O hydrogen bonds involving a nitrate O atom build up an infinite chain parallel to the a axis.
منابع مشابه
Bis[2-(pyrrolidin-2-yl)-1H-benzimidazole-κ2 N 2,N 3]copper(II) dinitrate dihydrate
In the title compound, [Cu(C(11)H(13)N(3))(2)](NO(3))(2)·2H(2)O, synthesized by hydro-thermal reaction of Cu(NO(3))(2) and racemic 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole, the Cu(II) atom lies on an inversion centre. The distorted octa-hedral Cu(II) environment contains two planar trans-related N,N-chelating 2-(pyrrolidin-2-yl)-1H-1,3-benzimidazole ligands in the equatorial plane and two monod...
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In the title compound, [Cd(NO(3))(2)(C(12)H(12)N(6))(2)](n), the Cd(II) cation is located on an inversion center and is six-coordinated by four N atoms from four 1,3-bis-[(1H-1,2,4-triazol-1-yl)meth-yl]benzene (L) ligands and two O atoms from two nitrate anions in a slightly distorted octa-hedral geometry. The ligands link different Cd(II) ions into a ribbon-like structure along [001]. Two O at...
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The title compound, [ZnBr(2)(C(11)H(13)N(3))], was synthesized by hydro-thermal reaction of ZnBr(2) and (S)-2-(pyrrolidin-2-yl)-1H-benzimidazole. The Zn(II) atom has a distorted tetra-hedral geometry and is coordinated by two N atoms from the chelating organic ligand and two terminal Br(-) anions. In the crystal structure, mol-ecules are linked into a chain along the [101] direction by N-H⋯Br a...
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